It is evident from some ahadees that among the names of Allah Ta'ala, there are names that most superior, that if anyone asks by them, Allah pak accepts their prayer. These names are called Ism Azam (greatest name). Following are some ahadees that tell about the greatest names.
عَنْ أَنَسِ بْنِ مَالِكٍ، قَالَ سَمِعَ النَّبِيُّ ـ صلى الله عليه وسلم ـ رَجُلاً يَقُولُ اللَّهُمَّ إِنِّي أَسْأَلُكَ بِأَنَّ لَكَ الْحَمْدَ لاَ إِلَهَ إِلاَّ أَنْتَ وَحْدَكَ لاَ شَرِيكَ لَكَ الْمَنَّانُ بَدِيعُ السَّمَوَاتِ وَالأَرْضِ ذُو الْجَلاَلِ وَالإِكْرَامِ فَقَالَ " لَقَدْ سَأَلَ اللَّهَ بِاسْمِهِ الأَعْظَمِ الَّذِي إِذَا سُئِلَ بِهِ أَعْطَى وَإِذَا دُعِيَ بِهِ أَجَابَ " .
It was narrated that Anas bin Malik said:
"The Prophet (saas) heard a man say: 'Allahumma! Inni as'aluka bi-anna lakal-hamd. La ilaha illa Anta, wahdaka la sharika laka. Al-Mannan. Badi'us-samawati wal-ard. Dhul-jalali wal-ikram (O Allah! I ask You by virtue of the fact that all praise is due to You; none has the right to be worshiped but You alone, and You have no partner or associate, the Bestower, the Originator of the heavens and the earth, the Possessor of majesty and honor.' He (saas) said: 'He has asked Allah by His Greatest Name which, if He is asked thereby He gives and if He is called upon thereby He answers.'"
عَنْ أَسْمَاءَ بِنْتِ يَزِيدَ، أَنَّ النَّبِيَّ صلى الله عليه وسلم قَالَ " اسْمُ اللَّهِ الأَعْظَمُ فِي هَاتَيْنِ الآيَتَيْنِِ : ( وإلَهُكُمْ إِلَهٌ وَاحِدٌ لاَ إِلَهَ إِلاَّ هُوَ الرَّحْمَنُ الرَّحِيمُ ) وَفَاتِحَةِ آلِ عِمْرَانَ (الم * اللَّهُ لاَ إِلَهَ إِلاَّ هُوَ الْحَىُّ الْقَيُّومُ ) " . قَالَ أَبُو عِيسَى هَذَا حَدِيثٌ حَسَنٌ صَحِيحٌ .
Asma bint Yazid narrated that the Prophet (ﷺ) said:
“Allah's greatest name is in these two Ayah: ‘And your deity is One deity, there is none who has the right to be worshipped but He, Ar-Raḥmān, Ar-Raḥīm.’ And the Opening of Al-`Imrān: ‘Alif. Lām. Mīm. Allah, None has the right to be worshipped but He, the Ever living, the Sustainer.’”
عَنِ الْقَاسِمِ، قَالَ اسْمُ اللَّهِ الأَعْظَمُ الَّذِي إِذَا دُعِيَ بِهِ أَجَابَ فِي سُوَرٍ ثَلاَثٍ الْبَقَرَةِ وَآلِ عِمْرَانَ وَطَهَ .
It was narrated that Al-Qasim said:
The Greatest Name of Allah, if He is called by which He will respond, is in three Surah: Al-Baqarah, Al 'Imran and Ta-Ha. (Hasan)Another chain for something similar from Al-Qasim, from Abu Umamah, from the Prophet (saas).
عَنْ عَبْدِ اللَّهِ بْنِ بُرَيْدَةَ الأَسْلَمِيِّ، عَنْ أَبِيهِ، قَالَ سَمِعَ النَّبِيُّ صلى الله عليه وسلم رَجُلاً يَدْعُو وَهُوَ يَقُولُ اللَّهُمَّ إِنِّي أَسْأَلُكَ بِأَنِّي أَشْهَدُ أَنَّكَ أَنْتَ اللَّهُ لاَ إِلَهَ إِلاَّ أَنْتَ الأَحَدُ الصَّمَدُ الَّذِي لَمْ يَلِدْ وَلَمْ يُولَدْ وَلَمْ يَكُنْ لَهُ كُفُوًا أَحَدٌ . قَالَ فَقَالَ " وَالَّذِي نَفْسِي بِيَدِهِ لَقَدْ سَأَلَ اللَّهَ بِاسْمِهِ الأَعْظَمِ الَّذِي إِذَا دُعِيَ بِهِ أَجَابَ وَإِذَا سُئِلَ بِهِ أَعْطَى "
Abdullah bin Buraidah Al Aslami narrated from his father, who said: “The Prophet (ﷺ) heard a man supplicating, and he was saying: ‘O Allah, indeed, I ask you by my testifying that You are Allah, there is none worthy of worship except You, the One, As-Samad, the one who does not beget, nor was begotten, and there is none who is like Him (Allāhumma innī as’aluka bi annī ashhadu annaka antallāh, lā ilāha illā ant, al-aḥaduṣ-ṣamad, alladhī lam yalid wa lam yūlad, wa lam yakun lahu kufuwan aḥad).” He said: “So he said: ‘By the One in Whose Hand is my soul, he has asked Allah by His Greatest Name, the one which if He is called upon by it, He responds, and when He is asked by it, He gives.’”