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#1 [Permalink] Posted on 9th December 2013 00:34
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Nothing new but the following BBC magazine article (by Justin Rowlatt) did bring back memories of conversations elsewhere. Insha'Allah, we can share all things 'gold' under this thread.

~~~

Why do we value gold?

Mankind's attitude to gold is bizarre. Chemically, it is uninteresting - it barely reacts with any other element. Yet, of all the 118 elements in the periodic table, gold is the one we humans have always tended to choose to use as currency. Why?

Why not osmium or chromium, or helium, say - or maybe seaborgium?

I'm not the first to ask the question, but I like to think I'm asking it in one of the most compelling locations possible - the extraordinary exhibition of pre-Columbian gold artefacts at the British Museum?

That's where I meet Andrea Sella, a professor of chemistry at University College London, beside an exquisite breastplate of pure beaten gold.

He pulls out a copy of the periodic table.



"Some elements are pretty easy to dismiss," he tells me, gesturing to the right-hand side of the table.

"Here you've got the noble gases and the halogens. A gas is never going to be much good as a currency. It isn't really going to be practical to carry around little phials of gas is it?

"And then there's the fact that they are colourless. How on earth would you know what it is?"

The two liquid elements (at everyday temperature and pressure) - mercury and bromine - would be impractical too. Both are also poisonous - not a good quality in something you plan to use as money. Similarly, we can cross out arsenic and several others.

Sella now turns his attention to the left-hand side of the table.

"We can rule out most of the elements here as well," he says confidently.

"The alkaline metals and earths are just too reactive. Many people will remember from school dropping sodium or potassium into a dish of water. It fizzes around and goes pop - an explosive currency just isn't a good idea."

A similar argument applies to another whole class of elements, the radioactive ones: you don't want your cash to give you cancer.

Out go thorium, uranium and plutonium, along with a whole bestiary of synthetically-created elements - rutherfordium, seaborgium, ununpentium, einsteinium - which only ever exist momentarily as part of a lab experiment, before radioactively decomposing.

Then there's the group called "rare earths", most of which are actually less rare than gold.

Unfortunately, they are chemically hard to distinguish from each other, so you would never know what you had in your pocket.

This leaves us with the middle area of the periodic table, the "transition" and "post-transition" metals.

This group of 49 elements includes some familiar names - iron, aluminium, copper, lead, silver.

But examine them in detail and you realise almost all have serious drawbacks.

We've got some very tough and durable elements on the left-hand side - titanium and zirconium, for example.

The problem is they are very hard to smelt. You need to get your furnace up into the region of 1,000C before you can begin to extract these metals from their ores. That kind of specialist equipment wasn't available to ancient man.

Aluminium is also hard to extract, and it's just too flimsy for coinage. Most of the others in the group aren't stable - they corrode if exposed to water or oxidise in the air.

Take iron. In theory it looks quite a good prospect for currency. It is attractive and polishes up to a lovely sheen. The problem is rust: unless you keep it completely dry it is liable to corrode away.

"A self-debasing currency is clearly not a good idea," says Sella.

We can rule out lead and copper on the same basis. Both are liable to corrosion. Societies have made both into money but the currencies did not last, literally.

So, what's left?

Of the 118 elements we are now down to just eight contenders: platinum, palladium, rhodium, iridium, osmium and ruthenium, along with the old familiars, gold and silver.

These are known as the noble metals, "noble" because they stand apart, barely reacting with the other elements.

They are also all pretty rare, another important criterion for a currency.

Even if iron didn't rust, it wouldn't make a good basis for money because there's just too much of it around. You would end up having to carry some very big coins about.

With all the noble metals except silver and gold, you have the opposite problem. They are so rare that you would have to cast some very tiny coins, which you might easily lose.

They are also very hard to extract. The melting point of platinum is 1,768C.

That leaves just two elements - silver and gold.

Both are scarce but not impossibly rare. Both also have a relatively low melting point, and are therefore easy to turn into coins, ingots or jewellery.

Silver tarnishes - it reacts with minute amounts of sulphur in the air. That's why we place particular value on gold.

It turns out then, that the reason gold is precious is precisely that it is so chemically uninteresting.

Gold's relative inertness means you can create an elaborate golden jaguar and be confident that 1,000 years later it can be found in a museum display case in central London, still in pristine condition.

So what does this process of elemental elimination tell us about what makes a good currency?

First off, it doesn't have to have any intrinsic value. A currency only has value because we, as a society, decide that it does.

As we've seen, it also needs to be stable, portable and non-toxic. And it needs to be fairly rare - you might be surprised just how little gold there is in the world.

If you were to collect together every earring, every gold sovereign, the tiny traces gold in every computer chip, every pre-Columbian statuette, every wedding ring and melt it down, it's guesstimated that you'd be left with just one 20-metre cube, or thereabouts.

But scarcity and stability aren't the whole story. Gold has one other quality that makes it the stand-out contender for currency in the periodic table. Gold is... golden.

All the other metals in the periodic table are silvery-coloured except for copper - and as we've already seen, copper corrodes, turning green when exposed to moist air. That makes gold very distinctive.

"That's the other secret of gold's success as a currency," says Sella. "Gold is unbelievably beautiful."

But how come no-one actually uses gold as a currency any more?

The seminal moment came in 1973, when Richard Nixon decided to sever the US dollar's tie to gold.

Since then, every major currency has been backed by no more than legal "fiat" - the law of the land says you must accept it as payment.

Nixon made his decision for the simple reason that the US was running out of the necessary gold to back all the dollars it had printed.

And here lies the problem with gold. Its supply bears no relation to the needs of the economy. The supply of gold depends on what can be mined.

In the 16th Century, the discovery of South America and its vast gold deposits led to an enormous fall in the value of gold - and therefore an enormous increase in the price of everything else.

Since then, the problem has typically been the opposite - the supply of gold has been too rigid. For example, many countries escaped the Great Depression in the 1930s by unhitching their currencies from the Gold Standard. Doing so freed them up to print more money and reflate their economies.

The demand for gold can vary wildly - and with a fixed supply, that can lead to equally wild swings in its price.

Most recently for example, the price has gone from $260 per troy ounce in 2001, to peak at $1,921.15 in September 2011, before falling back to $1,230 currently.

That is hardly the behaviour of a stable store of value.

So, to paraphrase Churchill, out of all the elements, gold makes the worst possible currency.

Apart from all the others.

Why is gold golden?

Gold's golden colour has been a mystery until very recently, says Andrea Sella.

The secret lies in its atomic structure. "Quantum mechanics alone doesn't explain it," he says.

"When you get to gold you find the atom is so heavy and the electrons move so fast that you now have to include Einstein's theory of relativity into the mathematics.

"It is only when you fold together quantum mechanics with relativity that suddenly you understand it."

Unlike other metals, which in their pure form reflect light straight back, gold molecules "slosh around a little," Sella says, with the result that gold "absorbs a bit of the blue spectrum light, giving the light that is reflected back its distinctive golden colour".



Gold - key facts:
  • Symbol: Au (from Latin aurum)
  • Atomic number: 79
  • Weight: 196.97
  • One of the "noble" metals that do not oxidise under ordinary conditions
  • Used in jewellery, electronics, aerospace and medicine
  • Most gold in the earth's crust is thought to derive from meteors
  • Biggest producers: China, Australia, US, Russia


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#2 [Permalink] Posted on 9th December 2013 00:45
A very cool AUDIO story on why gold beat out other elements. Sorry, there is a very short bit of instrumental music at the tail end of it (very brief). For those of you who would like to use technology to read the transcript of the audio for you... yep, a script --to audio -- to a transcript -- to audio again :^-) here is the

Copyright �2010 NPR. For personal, noncommercial use only. See Terms of Use. For other uses, prior permission required.

STEVE INSKEEP, host:

Gold is just one of the many elements listed on the periodic table of elements. It's the one we humans have prized that most, the one we've used as money for millennia. And yet, why gold? Why not Why not osmium or lithium or ruthenium? Today, our Planet Money team tackles that question. Here are and David Kestenbaum and Jacob Goldstein.

JACOB GOLDSTEIN: For those of you who havent seen a periodic table since 10th grade chemistry, it looks kind of like a bingo card. Each square has a different element in it. There's a square for carbon, one for tin and another for gold.

DAVID KESTENBAUM: And were going to go through it kind of like a game of bingo. Crossing stuff out that wont work as money. Jacob. I am rooting for osmium.

GOLDSTEIN: I got a good feeling about lithium.

KESTENBAUM: To help us out. We have a professional - Sanat Kumar. Sanat knows all the elements in the universe, because he is chair of the chemical engineering department at Columbia University.

GOLDSTEIN: Sanat starts at the far right side of the periodic table. The things there have a really appealing characteristic. Theyre not going to change. Theyre chemically stable.

MR. SANAT KUMAR (Chairman, Chemical Engineering Department, Columbia University): Helium, Neon, Argon, Krypton, Xenon, Radon.

KESTENBAUM: Those are the Noble Gases.

MR. KUMAR: Correct.

GOLDSTEIN: So they're good in way because they're nonreactive. They're not going to change. Big drawback: a gas.

(Soundbite of laughter)

GOLDSTEIN: You could have your money like in jar. But then if you open the jar, youd be broke.

MR. KUMAR: Basically, yeah.

(Soundbite of laughter)

KESTENBAUM: If you're playing at home, you can cross out the right most column - Helium down through Radon.

GOLDSTEIN: So now, Sanat swings to the left most column of the Periodic Table, and he gets over to my pick, Lithium.

MR. KUMAR: If you expose lithium to air it will cause a huge fire that can burn through concrete walls.

GOLDSTEIN: Money that spontaneously bursts into flames: Bad idea. And it turns out that most of the elements out there are like Lithium, pretty reactive.

KESTENBAUM: Not all burst into flames. But youll get chemical reactions. You know how Iron rusts? Something similar might happen.

GOLDSTEIN: Based on that, Sanat crosses out another 38 elements. Then we ask him about these two weird rows at the bottom: The Lanthanides and Actinides.

MR. KUMAR: The Actinides are all radioactive.

KESTENBAUM: So these are, again, things that would not make a very good coin because you'd come back a year later and two percent of it would be gone, or something.

MR. KUMAR: Or maybe more than. But in the process you'd be dead, as well.

KESTENBAUM: Okay. Alright, you convinced us. We can cross those off.

(Soundbite of laughter)

GOLDSTEIN: So now we're down from 118 elements to 30.

KESTENBAUM: Our requirements so far: One, not a gas; Two, doesnt corrode or burst into flames; Three, doesnt kill you.

GOLDSTEIN: Now, Sanat adds a new requirement. You want the thing you pick to be rare. And this eliminates a lot.

MR. KUMAR: Titanium, Vanadium, Chromium, Manganese, Iron...

KESTENBAUM: But you dont want an element that is too rare. And that is why my favorite, Osmium, the densest of all the elements, gets the axe.

MR. KUMAR: Osmium is probably one of the rarest things around.

KESTENBAUM: Why?

MR. KUMAR: I have no clue. It apparently comes in with meteorites.

GOLDSTEIN: Now we're now down to just five.

KESTENBAUM: Ladies and gentleman, our final contestants are...

(Soundbite of drumming)

KESTENBAUM: Rhodium, Palladium, Silver, Platinum and Gold.

GOLDSTEIN: So, using just chemistry, weve ended up with only what are called Precious Metals.

KESTENBAUM: But even here we can cross things out. Silver has been used as money. But Sanat says it tarnishes, so it's not the best choice.

GOLDSTEIN: And early civilizations couldnt have used Rhodium or Palladium. Those werent discovered until the early 1800s.

KESTENBAUM: That leaves Platinum and Gold. You can find both of them in rivers and streams.

GOLDSTEIN: But if you were in the ancient world and you wanted to make Platinum coins, you'd need some kind of crazy furnace from the future.

KESTENBAUM: The melting point for Platinum is over 3,000 degrees Fahrenheit. Gold, just by chance, melts at a much lower temperature.

MR. KUMAR: It's things like that. I mean it's all these things that brought it together that makes Gold unique.

KESTENBAUM: So imagine were on Earth. We get to rewind the clock and lay out history again. Maybe it goes a different way. Do you think it would go a different way? Or do you think, you know, probably again humans would settle on Gold?

MR. KUMAR: Im convinced, given what we know now and reconstructing it, for the Earth with every parameter we have, Gold is the sweet spot. And it would come out no other way.

KESTENBAUM: Today, of course, we dont use Gold as money. We just use paper -which burns, can be found anywhere but it doesnt kill you.

GOLDSTEIN: In a future story, well talk about how we got to paper money.

Im Jacob Goldstein.

KESTENBAUM: Im David Kestenbaum, NPR News.

INSKEEP: You're listening to MORNING EDITION from NPR News.

Copyright � 2010 NPR. All rights reserved. No quotes from the materials contained herein may be used in any media without attribution to NPR. This transcript is provided for personal, noncommercial use only, pursuant to our Terms of Use. Any other use requires NPR's prior permission. Visit our permissions page for further information.

NPR transcripts are created on a rush deadline by a contractor for NPR, and accuracy and availability may vary. This text may not be in its final form and may be updated or revised in the future. Please be aware that the authoritative record of NPR's programming is the audio.


Here is the PLANET MONEY article related to the audio (and transcript):

~~~

A Chemist Explains Why Gold Beat Out Lithium, Osmium, Einsteinium ...

The periodic table lists 118 different chemical elements. And yet, for thousands of years, humans have really, really liked one of them in particular: gold. Gold has been used as money for millennia, and its price has been going through the roof.

Why gold? Why not osmium, lithium, or ruthenium?

We went to an expert to find out: Sanat Kumar, a chemical engineer at Columbia University. We asked him to take the periodic table, and start eliminating anything that wouldn't work as money.

The periodic table looks kind of like a bingo card. Each square has a different element in it - one for carbon, another for gold, and so on.

Sanat starts with the far-right column of the table. The elements there have a really appealing characteristic: They're not going to change. They're chemically stable.

But there's also a big drawback: They're gases. You could put all your gaseous money in a jar, but if you opened the jar, you'd be broke. So Sanat crosses out the right-hand column.

Then he swings over to the far left-hand column, and points to one of the elements there: Lithium

"If you expose lithium to air, it will cause a huge fire that can burn through concrete walls," he says.

Money that spontaneously bursts into flames is clearly a bad idea. In fact, you don't want your money undergoing any kind of spontaneous chemical reactions. And it turns out that a lot of the elements in the periodic table are pretty reactive.

Not all of them burst into flames. But sometimes they corrode, start to fall apart.

So Sanat crosses out another 38 elements, because they're too reactive.

Then we ask him about those two weird rows at the bottom of the table. They're always broken out separately from the main table, and they have some great names - promethium, einsteinium.

But it turns out they're radioactive - put some einsteinium in your pocket, and a year later, you'll be dead.

So we're down from 118 elements to 30, and we've come up with a list of three key requirements:

  1. Not a gas.
  2. Doesn't corrode or burst into flames
  3. Doesn't kill you.


Now Sanat adds a new requirement: You want the thing you pick to be rare. This lets him cross off a lot of the boxes near the top of the table, because the elements clustered there tend to be more abundant.

At the same time, you don't want to pick an element that's too rare. So osmium - which apparently comes to earth via meteorites - gets the axe.

That leaves us with just five elements: rhodium, palladium, silver, platinum and gold. And all of them, as it happens, are considered precious metals.

But even here we can cross things out. Silver has been widely used as money, of course. But its reactive - it tarnishes. So Sanat says it's not the best choice.

Early civilizations couldn't have used rhodium or palladium, because they weren't discovered until the early 1800s.

That leaves platinum and gold, both of which can be found in rivers and streams.

But if you were in the ancient world and wanted to make platinum coins, you would have needed some sort of magic furnace from the future. The melting point for platinum is over 3,000 degrees Fahrenheit.

Gold happens to melt at a much lower temperature, which made it much easier for pre-industrial people to work with.

So we ask Sanat: If we could run the clock back and start history again, could things go a different way, or would gold emerge again as the element of choice?

"For the earth, with every parameter we have, gold is the sweet spot," he says. "It would come out no other way."

Today of course, we don't use gold as money; we use paper. It doesn't kill you, but it can be found in abundance and has an annoying tendency to burn when it comes into contact with a flame.

In a future story, we'll explain how we came to use paper money instead of gold.

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